910659-03-9Relevant articles and documents
Synthesis of Secondary and Tertiary Alkyl Boronic Esters by gem-Carboborylation: Carbonyl Compounds as Bis(electrophile) Equivalents
Shi, Dunfa,Wang, Lu,Xia, Chungu,Liu, Chao
supporting information, p. 10318 - 10322 (2018/07/31)
An unprecedent gem-carboborylation of aldehydes and ketones provides access to various secondary and tertiary alkyl boronic esters. The addition of B2pin2 to a carbonyl compound generates α-oxyl-substituted alkyl boron species. Organ
Facile formation of β-hydroxyboronate esters by a Cu-catalyzed diboration/Matteson homologation sequence
Moore, Cameron M.,Medina, Casey R.,Cannamela, Peter C.,McIntosh, Melissa L.,Ferber, Carl J.,Roering, Andrew J.,Clark, Timothy B.
supporting information, p. 6056 - 6059 (2015/01/16)
The copper-catalyzed diboration of aldehydes was used in conjunction with the Matteson homologation, providing the efficient synthesis of β-hydroxyboronate esters. The oxygen-bound boronate ester was found to play a key role in mediating the homologation
