91076-81-2

Upstream product

• 41467-26-9 1-(4-chlorophenyl)-3,3-bis(methylsulfanyl)-2-propen-1-one 
• 100-46-9 benzylamine 

Downstream Products

• 118792-63-5 2-Benzyl-4-(4-chloro-phenyl)-3-methylsulfanyl-2,3-dihydro-pyrano[3,4-c]pyrrole-1,6-dione 
• 135549-35-8 1-Benzyl-4-(4-chloro-benzoyl)-5-methylsulfanyl-1H-pyrrole-2,3-dione 
• 101459-98-7 5-p-chlorobenzoyl-4-methylthio-1,2-diphenylimidazole 
• 101476-59-9 2-amino-4-N-benzylamino-5-nitroso-6-p-chlorophenylpyrimidine 
• 101460-11-1 2-amino-4-N-benzylamino-6-p-chlorophenylpyrimidine 
• 135549-39-2 1-Benzyl-4-(4-chloro-benzoyl)-5-hydroxy-1H-pyrrole-2,3-dione 
• 91544-11-5 (4-Chloro-phenyl)-(4-methylsulfanyl-2-phenyl-thiazol-5-yl)-methanone 
• 91076-75-4 Benzyl-[5-(4-chloro-phenyl)-isoxazol-3-yl]-amine 

Relevant academic research and scientific papers

PhIO-Mediated Oxidative C═C Bond Cleavage and Reassembly toward Highly Functionalized Oxazolones

An efficient PhIO-mediated oxidative C═C bond cleavage and reassembly of enaminone toward oxazolone with high regioselectivity has been reported. DFT calculations revealed that the reaction proceeded through an oxygen atom transfer, C═C bond cleavage, alkylthio migration, and reassembly cascade. This strategy is highlighted by high atom and step economy with formation of five bonds in one pot and generation of a high-valued oxazolone skeleton under mild conditions.