910791-87-6Relevant academic research and scientific papers
Gold catalysis in the synthesis of azaindoles: Pyrrolo[2,3-b]pyridines and pyrrolo[2,3-b]pyrazines
Gala, Elena,Crdoba, Marta,Izquierdo, M. Luisa,lvarez-Builla, Julio
, p. 319 - 340 (2014/12/11)
The synthesis of substituted 1-benzyl-1H-pyrrolo[2,3-b]pyridines and 5-benzyl-5H-pyrrolo- [2,3-b]pyrazines has been performed by cycloisomerization of the corresponding N-benzyl- 3-alkynyl-5-arylpyridin(or pyrazin)-2-yl amines with AuCl3. Alkyn
A new class of pyrazolopyridine nucleus with fluorescent properties, obtained through either a radical or a Pd arylation pathway from N-azinylpyridinium N-aminides
Abet, Valentina,Nunez, Araceli,Mendicuti, Francisco,Burgos, Carolina,Alvarez-Builla, Julio
supporting information; experimental part, p. 8800 - 8807 (2009/04/11)
(Chemical Equation Presented) The synthesis of dipyridopyrazole and pyridopyrazolopyrazine derivatives - both of which incorporate a 3-aryl moiety - can be achieved in moderate yields by intramolecular radical arylation of pyridinium N-aminides using tris(trimethylsilyl)silane and azobisisobutyronitrile. Improved results were obtained on using Pd direct arylation in conjunction with microwave irradiation. A preliminary study into the fluorescent properties of the target compounds is also reported.
