911201-41-7Relevant academic research and scientific papers
Chiral phosphane alkenes (PALs): Simple synthesis, applications in catalysis, and functional hemilability
Piras, Elisabetta,Laeng, Florian,Rueegger, Heinz,Stein, Daniel,Woerle, Michael,Gruetzmacher, Hansjoerg
, p. 5849 - 5858 (2006)
A simple synthesis of a chiral phosphane alkene (PAL) involves: 1) palladium-catalyzed Suzuki coupling of 10-bromo-5H-dibenzo[a,d]cyclohepten-5-ol (1) with phenylboronic acid to give quantitatively 10-phenyl-5H-dibenzo[a,d] cyclohepten-5-ol (2); 2) reacti
Transition metal catalysts
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Page/Page column 5, (2010/11/27)
The present invention relates to stereoisomerically enriched phosphorus compounds, transition metal catalysts which can be prepared therefrom and their use in stereoselective catalytic processes, and also a process for preparing the stereoisomerically enr
