911207-05-1

Basic information

• Product Name: C₁₄⁽²⁾H₁₅N
• CAS NO: 911207-05-1
• Molecular Weight: 212.161
• Mol File: 911207-05-1.mol

Chemical Properties

• CAS DataBase Reference: C₁₄⁽²⁾H₁₅N(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄⁽²⁾H₁₅N(911207-05-1)
• EPA Substance Registry System: C₁₄⁽²⁾H₁₅N(911207-05-1)

Safety Data

• Hazardous Substances Data: 911207-05-1(Hazardous Substances Data)

Upstream product

• 17901-93-8 benzaldehyde-d6 
• 167750-79-0 α,α,2,3,4,5,6-heptadeuterobenzylamine 

Downstream Products

• 911207-06-2 C₂₁⁽²⁾H₁₄H₉ON 
• 610299-84-8 C₂₁H₉⁽²⁾H₁₄NS 

Relevant articles and documents

Neutron diffraction analysis of deuterium transfer in chiral β-thiolactam formation in the crystalline state

Since N,N-dibenzyl-1-cyclohexenecarbothioamide is photoisomerized to the optically active β-thiolactam with the retention of the single-crystal form, the mechanism of chirality induction was identified by X-ray crystal structure analyses during the process of the reaction [Hosoya et al. (2002). Bull. Chem. Soc. Jpn, 75, 2147-2151]. In order to clarify the mechanism of hydrogen transfer in the reaction, the H atoms of the benzyl groups were replaced with deuterium atoms. The crystal structure after photoisomerization was analyzed by neutron diffraction. One of four deuterium atoms of the two benzyl groups is transferred to the C atom of the cyclohexene ring. The absolute configuration of the -C*HD- group (chiral methylene) in the photoproduct β-thiolactam revealed that the deuterium atom occupies the equatorial position. This suggests that the deuterium atom is not transferred from the benzyl group of a neighbouring molecule, but from one of the benzyl groups within the molecule.