91129-87-2Relevant articles and documents
One Dimensional Copper(II) Coordination Polymers: Crystal Engineering through Variable Types of Linkage [1]
Saalfrank, Rolf W.,Harbig, Roland,Struck, Oliver,Hampel, Frank,Peters, Eva Maria,Peters, Karl,Von Schnering, Hans Georg
, p. 125 - 134 (1997)
Reaction of a methanolic copper(II) acetate solution with tetrazolyl enol derivatives 2a or 2b leads to the formation of the corresponding 1D-coordination polymer 1∞[CuL2] 3a and pseudo 1D-coordination polymer [CuL2]2 3b, respectively. On the contrary, reaction of 2c with methanolic copper(II) acetate solution yields OH-bridged 1D-coordination polymer 1∞[CuL2(MeOH)2] 3c. Single-crystal X-ray diffraction of the supramolecular species 3 established unequivocally the structures of the stairlike coordination compounds. Reaction of a methanolic copper(II) acetate solution with amidotetrazole derivative 6 leads to the formation of the 1D-coordination polymer 1∞[CuL2] 7. The structure of 7 has been established by X-ray structure analysis.
