91231-91-3

Upstream product

• 99-91-2 para-chloroacetophenone 
• 100-52-7 benzaldehyde 

Downstream Products

• 96853-10-0 3-(4-chlorobenzoyl)-6-(4-chlorophenyl)-1-(3-methoxyphenyl)-4-phenyl-2(1H)-pyridinethione 
• 96853-11-1 3-(4-chlorobenzoyl)-1,6-bis(4-chlorophenyl)-4-phenyl-2(1H)-pyridinethione 
• 96853-09-7 3-(4-chlorobenzoyl)-6-(4-chlorophenyl)-1,4-diphenyl-2(1H)-pyridinethione 

Relevant academic research and scientific papers

A rapid approach toward synthesis of 1,3,5-triarylpent-2-ene-1,5-diones catalyzed by KF/Al2O3 and PEG-400 using microwave irradiation

A rapid and efficient method for the synthesis of 1,3,5-triarylpent-2-ene- 1,5-diones is described based on a low-cost and environmentally benign KF/Al2O3 and PEG-400 co-catalyst catalyst via open-ring reactions of 2,4,6- triarylpyrylium salts compounds under microwave irradiation conditions. The advantage of this method is satisfactory yields, short reaction time and the use of a cheaper, milder, and efficient catalyst. Finally, twelve α, β-unsaturated diones have been obtained in good to excellent yields by this procedure.

Pyridinethiones, X. - Preparation of Pentene-1,5-dione Enolates and of 3-Benzoyl-2(1H)-pyridinethiones

An effective synthesis of 3-benzoyl-2(1H)-pyridinethiones 5a-n from stable enol salts 4 of pentene-1,5-diones and isothiocyanates is described.An attempt to prepare a 3-acetyl-2(1H)-pyridinethione from the cyano compound 7 and CH3MgX yielded the ketimine