912350-69-7Relevant articles and documents
Syntheses and Structures of a Series of Acyclic Diaminocarbene Palladium(II) Complexes Derived from 3,4-Diaryl-1 H-pyrrol-2,5-diimines and Bisisocyanide Palladium(II) Complexes
Boyarskaya, Dina V.,Bulatov, Evgeny,Boyarskaya, Irina A.,Chulkova, Tatiana G.,Rassadin, Valentin A.,Tolstopjatova, Elena G.,Kolesnikov, Ilya E.,Avdontceva, Margarita S.,Panikorovskii, Taras L.,Suslonov, Vitalii V.,Haukka, Matti
supporting information, p. 300 - 309 (2019/01/11)
Reactions of 3,4-diaryl-1H-pyrrol-2,5-diimines with various bisisocyanide palladium(II) complexes were studied. The coupling proceeds with one isocyanide ligand to accomplish the acyclic diaminocarbene complexes. The structure of generated diaminocarbene
Versatile, fragrant, convertible isonitriles
Pirrung, Michael C.,Ghorai, Subir
, p. 11772 - 11773 (2007/10/03)
The metalation of oxazoles leads to ring opening to the isocyanoenolate that can be O-acylated to give the unsaturated isonitriles. These substances undergo conventional multicomponent reactions. The products of their reactions are readily converted to acyl substitution products by treatment with acid and a nucleophile. These unsaturated isonitriles are notable by their simple preparations and, unusually, their nonoffensive odors. Copyright
