91244-83-6Relevant academic research and scientific papers
On rearrangements by cyclialkylations of arylpentanols to 2,3-dihydro-1H-indene derivatives. Part 1. An unexpected rearrangement by the acid-catalyzed cyclialkylation of 4-(2-chlorophenyl)-2,4-dimethyl pentan-2-ol under formation of trans-4-chloro-2,3-dih
Blum, Roger,Giovannini, Edgardo,Hengartner, Urs,Vallat, Gabriel
, p. 1827 - 1840 (2007/10/03)
The acid-catalyzed cyclialkylation of 2,4-dimethyl-4-phenylpentan-2-ol led exclusively to the expected product, 2,3-dihydro-1,1,3,3-tetramethyl-1H-indene. However, analogous cyclialkylation of 4-(2-chlorophenyl)-2,4-dimethylpentan-2-ol (1) gave a ca. 1:1
