91259-93-7

Upstream product

• 105373-87-3 (1S,2R)-Cyclohex-4-ene-1,2-dicarboxylic acid di-tert-butyl ester 
• 820993-73-5 (1R,6S)-6-Azidocarbonyl-cyclohex-3-enecarboxylic acid tert-butyl ester 
• 91259-92-6 (1S,2R)-6-(tert-butoxycarbonyl)-3-cyclohexene-1-carboxylic acid 
• 4841-84-3 dimethyl cis-1,2,3,6-tetrahydrophthalate 
• 820993-72-4 1-(tert-butyl) 2-methyl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate 
• 31139-02-3 (1R,6S)-6-methoxycarbonyl-3-cyclohexene-1-carboxylic acid 
• 67-56-1 methanol 

Downstream Products

• 72351-21-4 (+)-fortamine dihydrochloride 
• 111515-86-7 1-N-benzyl-1,2:4,5-di-N,O-carbonylfortamine 
• 111515-81-2 methyl (1R,2R,4S,5R,6R)-4-<(benzyloxycarbonyl)amino>-5-hydroxy-9-methyl-8-oxo-9-aza-7-oxabicyclo<4.3.0>nonanecarboxylate 
• 111515-83-4 (1R,4S,5R,6R)-4-<(benzyloxycarbonyl)amino>-5-<(tert-butyldimethylsilyl)oxy>-9-methyl-8-oxo-9-aza-7-oxabicyclo<4.3.0>non-2-ene 
• 111515-85-6 1-N-benzyl-6-O-(tert-butyldimethylsilyl)-1,2:4,5-di-N,O-carbonylfortamine 
• 111515-82-3 (1R,2R,4S,5R,6R)-4-<(benzyloxycarbonyl)amino>-5-<(tert-butyldimethylsilyl)oxy>-9-methyl-8-oxo-9-aza-7-oxabicyclo<4.3.0>nonanecarboxylic acid 
• 124287-83-8 methyl (1R,2R,4S,5R,6R)-4-<(benzyloxycarbonyl)amino>-5-<(tert-butyldimethylsilyl)oxy>-9-methyl-8-oxo-9-aza-7-oxabicyclo<4.3.0>nonanecarboxylate 
• 111515-84-5 (1R,4S,5R,6R)-4-(N-benzyl-N-(benzyloxycarbonyl)amino)-5-<(tert-butyldimethylsilyl)oxy>-9-methyl-8-oxo-9-aza-7-oxabicyclo<4.3.0>non-2-ene 
• 124287-88-3 1-N-benzyl-1-N-(benzyloxycarbonyl)-6-O-(tert-butyldimethylsilyl)-4,5-N,O-carbonyl-3-de-O-methylfortamine 
• 111515-78-7 methyl (1R,2S,5S)-5-hydroxy-2-cyclohex-3-enecarboxylate 
• 111860-30-1 (1R,2S,5S)-5-Methanesulfonyloxy-2-(methoxycarbonyl-methyl-amino)-cyclohex-3-enecarboxylic acid methyl ester 
• 124287-87-2 (1R,4S,5R,6R)-4-<(benzyloxycarbonyl)amino>-2-bromo-5-<(tert-butyldimethylsilyl)oxy>-9-methyl-8-oxo-9-aza-7-oxabicyclo<4.3.0>nonane 
• 124287-86-1 methyl (1R,2S,5R)-5-chloro-2-cyclohex-3-enecarboxylate 
• 111515-87-8 methyl (1R,2S,5S)-5-hydroxy-2-<(methoxycarbonyl)amino>cyclohex-3-enecarboxylate 

Relevant academic research and scientific papers

An Enantioselective Synthesis of (-)-Fortamine

The aminocyclitol moiety of fortimicin A, (-)-fortamine, was synthesized in an enantioselective manner starting from the chiral half ester, easily available by the enantioselective hydrolysis of a symmetrical diester with pig liver esterase.The present ap

CREATION OF NOVEL CHIRAL SYNTHONS WITH ENZYMES AND APPLICATIONS TO NATURAL PRODUCT SYNTHESIS. 15. EFFICIENT INTRODUCTION OF CHIRAL CENTERS INTO CYCLOHEXANE RING.

The chiral half-ester 2 obtained by asymmetric hydrolysis of the symmetric diester 1 with pig liver esterase has been shown to be a versatile synthon for various chiral cyclohexane derivatives.