912935-40-1Relevant academic research and scientific papers
Enantioselective bromocyclization of allylic amides catalyzed by BINAP derivatives
Kawato, Yuji,Kubota, Akino,Ono, Hiromi,Egami, Hiromichi,Hamashima, Yoshitaka
, p. 1244 - 1247 (2015)
A highly enantioselective bromocyclization of allylic amides with N-bromosuccinimide (NBS) was developed with DTBM-BINAP as a catalyst, affording chiral oxazolines with a tetrasubstituted carbon center in high yield with up to 99% ee. By utilizing the bro
Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid
Mo, Jun,Xu, Lijin,Ruan, Jiwu,Liu, Shifang,Xiao, Jianliang
, p. 3591 - 3593 (2008/09/20)
In contrast to almost all of the known examples of Heck arylation of unsaturated alcohols, which yield predominately β-arylated products, arylation under the Pd-DPPP catalysis in ionic liquid leads preferentially to aryl substitution at the α carbon, prov
