913059-40-2Relevant academic research and scientific papers
Syntheses, characterisation and structure of new diazoketiminato chelates of palladium(II) incorporating a tridentate (N,N,N) azo ligand
Patra, Debprasad,Pratihar, Jahar lal,Shee, Biswaranjan,Pattanayak, Poulami,Chattopadhyay, Surajit
, p. 2637 - 2642 (2006)
The 1N-(2-pyridyl-2-methyl)-2-arylazo aniline, HL [where HL = ArN{double bond, long}NC6H4N(H)(CH2C5H4N); Ar{double bond, long}C6H5 (for HL1) or p-MeC6H4 (for HL2) or p-ClC6H4 (for HL3)], ligands were prepared by treating the appropriate 2-(arylazo) aniline with 2-chloromethyl pyridine. Reactions of Na2PdCl4 with HL afforded (L)PdCl complexes. HL binds palladium(II) in a tridentate fashion (N,N,N) forming a new diazoketiminato chelate, dissociating the amino proton. The X-ray structure of (L1)PdCl was determined.
