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Magnesium bis(tetrahydridogallate(III)): Structure and reaction with tert-butyl alcohol
Veith, Michael,Burkhart, Markus,Huch, Volker
, p. 5544 - 5546 (2006)
(Figure Presented) Unknown terrain: Mg(GaH4)2· 4 OEt2 (see molecular structure; blue Ga, green Mg, red O, gray C, white H) can be regarded as a parent compound for the essentially unexplored group of alkaline-earth tetrahydridogallates. Reaction of Mg-(GaH 4)2·4 OEt2 with tert-butyl alcohol leads to {Mg(OtBu)[GaH2(OtBu)2]}2.
