91309-69-2Relevant academic research and scientific papers
Photolysis of 3-Chlorodiazirine in the Presence of Alkenes: Orientational Factors in the Intermolecular Interception of Chlorocarbene by Alkenes
Tomioka, Hideo,Hayashi, Norihiro,Izawa, Yasuji,Liu, Michael T. H.
, p. 476 - 478 (1984)
The stereochemistry of the 1,2-H shift of photolytically generated benzylchlorocarbene is significantly affected by aryl substituents and by the addition of an alkene.
INVESTIGATIONS ON REACTIONS OF CHLORINE DIOXIDE AND SODIUM CHLORITE WITH ORGANIC COMPOUNDS. PART XXXV. REACTIONS OF CHLORINE DIOXIDE WITH RING-SUBSTITUTED STYRENES
Kwiecien, Halina,Jalowiczor, Jozef
, p. 811 - 824 (2007/10/02)
Reactions of chlorine dioxide with ring substituted styrenes (1a-n) in carbon tetrachloride at 52-54 deg C were studied.The reaction products were isolated and characterised.It has been found that methyl-, chloro-, nitrostyrenes and 4-methoxystyrene are attacked by chlorine dioxide exclusively on the vinyl group, to yield the corresponding α-chloroacetophenones (2), diastereoisomers of β-chlorostyrene (6,7), oxidation products (8,9) and some polymers.Oxidation of its phenolic hydroxyl groups and vinyl polymerization took place in hydroxystyrenes.
