Photolysis of 3-Chlorodiazirine in the Presence of Alkenes: Orientational Factors in the Intermolecular Interception of Chlorocarbene by Alkenes

DOI: 10.1039/c39840000476

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 476 - 478 (1984)

Update date:2022-08-04

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Authors:

Tomioka, Hideo

Hayashi, Norihiro

Izawa, Yasuji

Liu, Michael T. H.

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Article abstract of DOI:10.1039/c39840000476

The stereochemistry of the 1,2-H shift of photolytically generated benzylchlorocarbene is significantly affected by aryl substituents and by the addition of an alkene.

Full text of DOI:10.1039/c39840000476

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