913371-18-3Relevant articles and documents
Coordination chemistry of perhalogenated cyclopentadienes and alkynes, xxix. the reaction of ni(0) and pt(0) phosphane complexes with trichloroethene, hexachloro- and hexabromocyclopentadiene
Suenkel, Karlheinz,Bernhartzeder, Stefanie,Birk, Uwe
, p. 557 - 563,7 (2020/08/31)
Trichloroethene reacts with [Pt(PPh3)2(C2H4)] at first to the p complex [Pt(PPh3)2(h2-C2HCl3)] (1a), which isomerizes via the cis-isomer to the insoluble trans-[Pt(Cl)(h1-CH=CCl2)(PPh3)2] (2a). Both 1a and 2a react with PBu3 to the corresponding tributylp