913636-31-4Relevant academic research and scientific papers
Stereoselective synthesis of (S,S)-palythazine from D-mannitol
Nagaiah, Kommu,Srinivasu, Khandregula,Kumar, S. Praveen,Basha, Jeelani,Yadav, Jhillu Singh
experimental part, p. 885 - 889 (2010/10/21)
Exploiting the symmetry element, an asymmetric synthesis of (S,S)-palythazine was accomplished with (R)-glyceraldehyde acetonide as the chiral precursor. The prominent steps involved stereoselective Barbier allylation, ring-closing metathesis, regioselect
The first total synthesis of (S)-clavulazine from d-mannitol
Kumar, S. Praveen,Nagaiah,Chorghade, Mukund S.
, p. 7149 - 7151 (2007/10/03)
The first total synthesis of the marine natural product, (S)-clavulazine has been accomplished. d-Mannitol was used as a chiral starting material. Enantioselective zinc-mediated allylation, and ring-closing metathesis are the key steps in the synthesis. S
