913698-95-0Relevant academic research and scientific papers
Dienamine catalysis: Organocatalytic asymmetric γ-amination of α,β-unsaturated aldehydes
Bertelsen, Soren,Marigo, Mauro,Brandes, Sebastian,Diner, Peter,Jorgensen, Karl Anker
, p. 12973 - 12980 (2006)
A new concept in organocatalysis is presented, the direct asymmetric γ-functionalization of α,β-unsaturated aldehydes. We disclose that secondary amines can invert the usual reactivity of α,β- unsaturated aldehydes, enabling a direct γ-amination of the ca
