91375-47-2Relevant academic research and scientific papers
Silylamines in Organic Synthesis. Facile Synthetic Routes to Unsaturated Protected Primary Amines.
Corriu, Robert J. P.,Huynh, Vilam,Iqbal, Javed,Moreau, Joel J. E.,Vernhet, Claude
, p. 6231 - 6244 (2007/10/02)
The reactions of lithium N,N-bis(trimethylsilyl)aminomethyl acetylide with electrophilic reagents offered a short preparation of substituted and functional propargyl amines.These are shown to be useful precursors of various saturated protected primary amines.Addition reactions to the carbon-carbon triple bond or isomerisation reactions gave rise to allylic, dienic and α-allenic amines. Keywords: Silylamines; propargylamines, α-allenylamines; N,N-bis(silyl)dienamines.
USES OF Si-N BONDS IN ORGANIC SYNTHESIS. A DIRECT SYNTHESIS OF FUNCTIONAL PROTECTED PROPARGYLIC PRIMARY AMINES.
Corriu, Robert J. P.,Huynh, Vilam,Moreau, Joel J. E.
, p. 1887 - 1890 (2007/10/02)
An easy route to lithium N,N-bis(trimethylsilyl)aminomethylacetylide 1 is described.Reactions of 1 with electrophiles give rise to various protected primary amines.
