913832-80-1

Basic information

• Product Name: C₃₂H₅₀O₄Si
• Synonyms: C₃₂H₅₀O₄Si
• CAS NO: 913832-80-1
• Molecular Weight: 526.832
• Mol File: 913832-80-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₂H₅₀O₄Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₂H₅₀O₄Si(913832-80-1)
• EPA Substance Registry System: C₃₂H₅₀O₄Si(913832-80-1)

Safety Data

• Hazardous Substances Data: 913832-80-1(Hazardous Substances Data)

Upstream product

• 7396-44-3 benzyl diethylphosphonoacetate 
• 913832-79-8 C₂₄H₄₄O₂Si 
• 913832-78-7 C₁₅H₂₂O₂ 
• 226915-61-3 (3R,3aS,4S,4aR,8aS,9aR)-3-methyl-1-oxo-decahydronaphtho[2,3-c]furan-4-carbaldehyde 

Downstream Products

• 913832-81-2 C₃₂H₄₉BrO₄Si 

Relevant articles and documents

Total synthesis of (-)-himgaline

The first total synthesis of (-)-himgaline and a highly enantioselective synthesis of its congener (-)-GB 13 are described. Decarboxylative aza-Michael reaction of the hexacyclic lactone precursor under acidic conditions, followed by basic workup, yielded (-)-GB 13 in 80% yield. Cyclization of (-)-GB 13 to oxohimgaline under acidic conditions, followed by internally coordinated sodium triacetoxyborohydride reduction, gave (-)-himgaline as the exclusive product. Copyright