914083-45-7

Upstream product

• 914083-43-5 {(S)-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-[(4S,5S)-2,2-dimethyl-5-((S)-1-methyl-6-oxo-hexyl)-[1,3]dioxolan-4-yl]-methyl}-carbamic acid tert-butyl ester 
• 3462-97-3 (4-methoxybenzyl)triphenylphosphonium bromide 
• 7540-51-4 (S)-3,7-dimethyl-6-octen-1-ol 
• 84717-44-2 2-((S)-3,7-Dimethyl-oct-6-enyloxy)-tetrahydro-pyran 
• 137765-95-8 (S)-4-Methyl-6-(tetrahydro-pyran-2-yloxy)-hexanal 
• 914083-38-8 Trifluoro-methanesulfonic acid (S)-[(4R,5S)-5-((S)-6-benzyloxy-1-methyl-hexyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl ester 
• 914083-32-2 (2S,3S)-3-[(4S,5S)-5-((S)-6-Benzyloxy-1-methyl-hexyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-dihydroxy-propionic acid ethyl ester 
• 914083-41-3 {(S)-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-[(4S,5S)-5-((S)-6-hydroxy-1-methyl-hexyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-methyl}-carbamic acid tert-butyl ester 
• 914083-36-6 (S)-[(4S,5S)-5-((S)-6-Benzyloxy-1-methyl-hexyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol 
• 914083-40-2 (4S,5S)-4-[(S)-Azido-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-5-((S)-6-benzyloxy-1-methyl-hexyl)-2,2-dimethyl-[1,3]dioxolane 
• 914083-34-4 (1S,2R)-1-[(4S,5S)-5-((S)-6-Benzyloxy-1-methyl-hexyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-propane-1,2,3-triol 
• 914083-27-5 (E)-3-[(4S,5S)-5-((S)-6-Benzyloxy-1-methyl-hexyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acrylic acid ethyl ester 
• 914083-25-3 (E)-(4S,5S,6S)-11-Benzyloxy-4,5-dihydroxy-6-methyl-undec-2-enoic acid ethyl ester 
• 914083-19-5 (S)-11-Benzyloxy-4-hydroxy-6-methyl-undec-2-ynoic acid ethyl ester 

Downstream Products

• 914083-48-0 ((1S,2S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-1-{(4S,5S)-5-[(E)-(S)-7-(4-methoxy-phenyl)-1-methyl-hept-6-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-propyl)-carbamic acid tert-butyl ester 
• 914083-50-4 ((1S,2S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methoxymethoxy-1-{(4S,5S)-5-[(E)-(S)-7-(4-methoxy-phenyl)-1-methyl-hept-6-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-propyl)-carbamic acid tert-butyl ester 
• 914083-46-8 ((1S,2S)-2,3-Dihydroxy-1-{(4S,5S)-5-[(E)-(S)-7-(4-methoxy-phenyl)-1-methyl-hept-6-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-propyl)-carbamic acid tert-butyl ester 

Relevant academic research and scientific papers

Stereoselective synthesis of the C1-C20 segment of the microsclerodermins A and B

An enantioselective route for the synthesis of key fragment C1-C20 resident in microsclerodermins A and B is described. The route features deoxygenative rearrangement of an hydroxy-alkynoate and a highly enantio- and diastereo-controled iterative dihydrox