91411-15-3

Upstream product

• 6435-78-5 N-tosylpyrrolidine 
• 227018-66-8 (E)-6-chloro-1-phenyl-2-hexen-1-one 
• 20913-05-7 (Benzoylmethylene)triphenylphosphorane 
• 70-55-3 toluene-4-sulfonamide 
• 227018-69-1 (E)-6-iodo-1-phenyl-2-hexen-1-one 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 86658-76-6 1-<(4-methyl-phenyl)sulfonyl>-2-methoxy-pyrrolidine 

Relevant academic research and scientific papers

N-(4-methylbenzenesulfonyl)- pyrrolidines and piperidines by a tandem S(N)2-Michael addition reaction

A tandem S(N)2-Michael addition sequence has been developed for the preparation of N-(4-methylbenzenesulfonyl)- pyrrolidines and piperidines bearing functionalized side chains at C-2.

Electroorganic Chemistry. 81. Anodic Oxidation of Sulfonamides and Amidophosphates

Oxidation peak potentials of sulfonamides and amidophosphates were measured in acetonitrile and compared with the corresponding amides and carbamates.The results showed that the order of easiness of oxidation was amides > carbamates > amidophosphates > sulfonamides.Furthermore, the reaction of silyl enol ethers or trimethyl phosphite with anodically α-methoxylated sulfonamides or amidophosphates has clearly shown that the α-methoxylated compounds are useful starting materials in organic synthesis.For example, optically active L-tryptophan was synthesized from α-methoxylated N-(p-tolylsulfonyl)-L-proline ester.