914388-35-5Relevant academic research and scientific papers
Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: An efficient synthesis of phosphaguanidines
Ma, Wangyang,Xu, Ling,Zhang, Wen-Xiong,Xi, Zhenfeng
, p. 7649 - 7655 (2015/10/12)
The phosphaguanylation reaction of phosphines with carbodiimides catalyzed by half-sandwich yttrium tris(trimethylsilylmethyl) ate complexes is achieved for the first time to efficiently prepare phosphaguanidines. The catalyst system of the yttrium ate complex displays better catalytic activity than those of neutral yttrium complexes.
Half-sandwich o-N,N-dimethylaminobenzyl complexes over the full size range of group 3 and lanthanide metals. synthesis, structural characterization, and catalysis of phosphine P-H bond addition to carbodiimides
Zhang, Wen-Xiong,Nishiura, Masayoshi,Mashiko, Tomohiro,Hou, Zhaomin
experimental part, p. 2167 - 2179 (2009/04/06)
The acid-base reactions between the rare-earth metal (Ln) tris(ortho-N,N-dimethylaminobenzyl) complexes [Ln(CH2C 6H4NMe2-o)3] with one equivalent of the silylene-linked cyclopentadiene-amine ligand (C
