915193-63-4Relevant academic research and scientific papers
An expeditious synthesis of N-acetylneuraminic acid α-C-glycosyl derivatives ("α-C-glycosides") from the anomeric acetates
Malapelle, Adeline,Coslovi, Anna,Doisneau, Gilles,Beau, Jean-Marie
, p. 3145 - 3157 (2008/02/09)
The reductive metallation of the readily available peracetylated derivatives of methyl N-acetylneuraminate 3a and 3b by samarium diiodide without any additive generates the corresponding anomeric samarium(III) organometallics. These intermediates react ef
Anomeric acetates of N-acetylneuraminic acid are useful C-sialyl donors in samarium-mediated reformatsky coupling reactions
Malapelle, Adeline,Abdallah, Zouleika,Doisneau, Gilles,Beau, Jean-Marie
, p. 6016 - 6020 (2007/10/03)
(Chemical Equation Presented) Teaching an old molecule new tricks: A new solution for an expeditious C-sialylation from N-acetylneuraminic acid involves the use of the peracetylated derivative 1, a very common starting material prepared 40 years ago in He
