915237-92-2Relevant academic research and scientific papers
Reaction of ene-bis(phosphinylallenes): [2+2] versus [4+2] cycloaddition
Kitagaki, Shinji,Okumura, Yuki,Mukai, Chisato
, p. 10311 - 10320 (2007/10/03)
Reaction of ene-bis(phosphinylallenes), derived from ene-bis(propargyl alcohols) and chlorodiphenylphosphine, was investigated. Benzene-bridged bis(phosphinylallenes) exclusively gave intramolecular [2+2] cycloadducts in the presence of dimethyl fumarate
Tuning Rate of the Bergman Cyclization of Benzannelated Enediynes with Ortho Substituents
Alabugin, Igor V.,Manoharan, Mariappan,Kovalenko, Serguei V.
, p. 1119 - 1122 (2007/10/03)
matrix presented The Bergman cyclization of benzannelated enediynes is highly sensitive to ortho substitution. This finding opens possibilities for the rational design of conformer-specific and pH-dependent DNA-cleaving agents.
