915286-01-0Relevant academic research and scientific papers
Inversion of diastereoselectivity depending on substrate concentration in baker's yeast catalyzed reduction of σ-symmetrical 1,3-cyclopentadiones and 1,3-cyclohexadiones
Katoh, Takahiro,Mizumoto, Shinsuke,Fudesaka, Masato,Nakashima, Yuki,Kajimoto, Tetsuya,Node, Manabu
, p. 2176 - 2182 (2006)
Inversion of diastereoselectivity caused by a change in substrate concentration was first observed in baker's yeast catalyzed reduction of σ-symmetrical 2,2-dialkylated cyclopentan-1,3-diones 1,2 and cyclohexan-1,3-dione 20. The selectivity altered by deg
