915304-99-3Relevant articles and documents
Synthesis of (±)-aureol by bioinspired rearrangements
Rosales, Antonio,Mu?oz-Bascón, Juan,Roldan-Molina, Esther,Rivas-Bascón, Nazaret,Padial, Natalia M.,Rodríguez-Maecker, Roman,Rodríguez-García, Ignacio,Oltra, J. Enrique
, p. 1866 - 1870 (2015)
A bioinspired and sustainable procedure for the straightforward synthesis of (±)-aureol has been achieved in eight steps (14% overall yield) from epoxyfarnesol. The key steps are the titanocene(III)-catalyzed radical cascade cyclization of an epoxyfarneso