915314-44-2Relevant academic research and scientific papers
Controlled di-lithiation enabled synthesis of phosphine-sulfonamide ligands and implications in ethylene oligomerization
Mote, Nilesh R.,Gaikwad, Shahaji R.,Khopade, Kishor V.,Gonnade, Rajesh G.,Chikkali, Samir H.
supporting information, p. 3717 - 3723 (2021/03/22)
Catalyst design for ethylene oligomerization has attracted significant interest. Herein, we report the synthesis of phosphine-sulfonamide-derived palladium complexes and examine their performance in ethylene oligomerization. Arresting a dilithiation intermediate ofN-(2-bromophenyl)-4-methylbenzenesulfonamide (1) at ?84 °C selectively producedN-(2-(bis(2-methoxyphenyl)phosphanyl)phenyl)-4-methylbenzenesulfonamide (L1A). However, the same reaction at ?41 °C delivered a different ligand; 2-(bis(2-methoxyphenyl)phosphanyl)-4-methyl-N-phenylbenzenesulfonamide (L2A). The generality of our strategy has been demonstrated by preparingN-(2-(diphenylphosphanyl)phenyl)-4-methylbenzenesulfonamide (L1B) and 2-(diphenylphosphanyl)-4-methyl-N-phenylbenzenesulfonamide (L2B). Subsequently,L1AandL1Bwere treated with a palladium precursor to yield 5-membered complexesC1andC2, respectively. In contrast,L2Aupon treatment with palladium produced a 6-membered metal complexC3. Thus, a small library of 7 palladium complexes (C1-C7) were synthesized by varying the donor moiety (pyridine, DMSO, and acetonitrile). The identity of palladium complexes was unambiguously ascertained using a combination of spectroscopic and analytical methods, including single-crystal X-ray diffraction. The performance of the complexesC1-C7was investigated in ethylene oligomerization and almost all of them were found to be active. The resultant ethylene oligomers were characterized using1H and13C NMR, MALDI-ToF-MS, and GPC. Detailed screening of reaction parameters revealed 100 °C and 40 bars ethylene to be optimal conditions. ComplexC5outperformed other complexes and produced ethylene oligomers with a molecular weight of 1000-1900 g mol?1
Highly chemo- and regioselective C-P cross-coupling reaction of quinone imine ketals with Ar2P(O)H to construct: Ortho -amino triarylphosphine derivatives
Liu, Teng,Li, Yongqin,Cheng, Feixiang,Shen, Xianfu,Liu, Jianjun,Lin, Jun
, p. 3536 - 3541 (2019/07/10)
A highly chemo- and regioselective approach for the construction of ortho-amino triarylphosphine oxides has been achieved through a C-P cross-coupling reaction involving quinone imine ketals (QIKs) with Ar2P(O)H and catalyzed via a Lewis base. This alternative protocol provided a wide substrate scope with excellent yields (82-95%), and a variety of ortho-amino triarylphosphines were obtained with high yields (87-95%) via further reductive reaction. Furthermore, this reaction could be scaled-up and several synthetic transformations were accomplished for the construction of functionalized organophosphorus.
Iridium(III)-Catalyzed C H Amidation of Arylphosphoryls Leading to a P-Stereogenic Center
Gwon, Donghyeon,Lee, Donggun,Kim, Jiyu,Park, Sehoon,Chang, Sukbok
supporting information, p. 12421 - 12425 (2016/08/25)
Direct C H amidation of arylphosphoryl compounds has been developed by using an IrIIIcatalyst system under mild conditions. A wide range of substrates could be employed with high functional-group tolerance. This procedure was successfully applied for the first time to the asymmetric reaction giving rise to a P-chirogenic center with a high diastereomeric ratio of up to 19:1 (90 % de).
Synthesis of a chelating hexadentate ligand with a P3N 3 donor set. Crystal and molecular structure of [OC-6-22]-[Co{(R P*,RP*,RP*)-CH 3C(CH2PPhC6H4NH2
Bennett, Justine,Doyle, Roy J.,Salem, Geoffrey,Willis, Anthony C.
, p. 4614 - 4622 (2007/10/03)
The first structurally authenticated example of a hexadentate chelating tertiary phosphine in which all six donors are bound to a single metal centre is described. The multidentate ligand (RP*,RP*, RP*)- and (RP
