67405-21-4

Basic information

• Product Name: Benzenamine, 2-(phenylphosphino)-
• CAS NO: 67405-21-4
• Molecular Formula: C12H12NP
• Molecular Weight: 201.208
• Mol File: 67405-21-4.mol

Chemical Properties

• CAS DataBase Reference: Benzenamine, 2-(phenylphosphino)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 2-(phenylphosphino)-(67405-21-4)
• EPA Substance Registry System: Benzenamine, 2-(phenylphosphino)-(67405-21-4)

Safety Data

• Hazardous Substances Data: 67405-21-4(Hazardous Substances Data)

Upstream product

• 65423-44-1 (2-diphenylphosphino)benzeneamine 
• 615-43-0 2-iodophenylamine 
• 638-21-1 phenylphosphane 

Downstream Products

• 434319-11-6 1,4-bis[(2-aminophenyl)phenylphosphino]butane 
• 434319-12-7 1,5-bis[(2-aminophenyl)phenylphosphino]pentane 
• 199343-31-2 [SP-4-2]-bis[(+/-)-(2-aminophenyl)phenylphosphine-P]dimethylplatinum(II) 
• 1207278-00-9 (2-aminophenyl)chlorophenylphosphine hydrochloride 
• 1207278-01-0 (+/-)-3-phenyl-1,3-dihydrobenzo[1,3]azaphosphol-2-one 
• 1207278-06-5 1,2-bis[(2-aminophenyl)phenylphosphino]ethane 
• 195989-84-5 (+/-)-(2-aminophenyl)(2-chlorophenyl)methylphosphine 
• 31238-62-7 2-methylphosphanyl-aniline 
• 160952-03-4 (R*,R*/S*)-1,3-Bis<<2-(methylphenylphosphino)phenyl>amino>propane 
• 434319-13-8 1,6-bis[(2-aminophenyl)phenylphosphino]hexane 
• 174468-98-5 1,3-bis<(2-aminophenyl)phenylphosphino>propane 
• 915314-44-2 N-[2-(diphenylphosphanyl)phenyl]-4-methylbenzenesulfonamide 

Relevant articles and documents

Synthesis of a chelating hexadentate ligand with a P3N 3 donor set. Crystal and molecular structure of [OC-6-22]-[Co{(R P*,RP*,RP*)-CH 3C(CH2PPhC6H4NH2

The first structurally authenticated example of a hexadentate chelating tertiary phosphine in which all six donors are bound to a single metal centre is described. The multidentate ligand (RP*,RP*, RP*)- and (RP

A novel access to tertiary and secondary ortho-aminophenylphosphines by protected group synthesis and palladium catalyzed P-C coupling reactions

The dilithium salt 1a formed by ortho-metallation of N-tert-butoxycarbonylaniline (BOC-aniline) 1 with two equivalents of tert-butyllithium reacts with the chlorophosphines Ph3-n,PCln, (n = 1 - 3) to yield the BOC protected ortho-aminophenylphosphines 2 - 4 in high yields. On deprotection of 2 - 4 with trimethylchlorosilane in the presence of phenol the HCl adducts of the ortho-aminophenylphosphines 5 - 7 are formed which may be deprotonated with KOH or NaOH to give the neutral phosphines 5a - 7a. The novel secondary phosphine 8 with two ortho-aminophenyl groups is accessible by cleavage of the P-C bond in 7a with metallic lithium and subsequent hydrolysis. The bifunctional P,N ligands 6 or 6a are alternatively accessible by Pd-catalyzed P-C coupling of ortho-iodoaniline with phenylphosphine. If a 1:1 stoichiometry is employed in the coupling reaction of ortho-iodoaniline and phenylphosphine the chiral secondary phosphine 9 is formed.

Synthesis, Resolution and Reactions of (+/-)-(2-Aminophenyl)methylphenylphosphine. Crystal and Molecular Structure of (R*,R*,S*,R*)-(+/-)-(1,3-Bisamino>propane)nickel(II) Perchlorate

Asymmetric bidentate (+/-)-(2-aminophenyl)methylphenylphosphine has been prepared in 80percent yield from (2-aminophenyl) diphenylphosphine via the secondary phosphine (+/-)-(2-aminophenyl)phenylphosphine.The chiral tertiary phosphine has been resolved by

Completely Stereoselective Synthesis of a Chiral Quadridentate Ligand with As2NP Donor Atoms. Crystal and Molecular Structure of *,S*)>-(+/-)-Dichloro--2-<(2-aminophenyl)methylphosph

Reaction of (+/-)-(2-aminophenyl)(2-chlorophenyl)methylphosphine with sodium (2-dimethylarsinophenyl)methylarsenide is completely stereoselective giving (R*,S*)-1--2-(2-aminophenyl)methylphosphi