91540-10-2Relevant academic research and scientific papers
THE INFLUENCE OF SIDE-CHAINS ON THE COMPLEXATION OF CATIONS BY CROWNS. SYNTHESIS AND Cu(II) COMPLEXATION OF N,N'-DIARYL-DIAZA-18-CROWN-6
Sonveaux, E.
, p. 793 - 798 (2007/10/02)
Various N,N'-diaryl derivatives of 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane were synthesized. 7,16-diphenyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane had only a low affinity for cations.On the contrary, diamide derivatives of 7,16-di-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane were deprotonated by Cu(II) and formed stable chelates.Spectral data suggest that monodeprotonation gives dissymmetric 1:1-complexes and dideprotonation gives symmetric 1:1-complexes.
