91597-62-5

Basic information

• Product Name: Cyclobutanecarbonitrile, 3-ethenyl-3-methoxy-, cis-
• CAS NO: 91597-62-5
• Molecular Formula: C8H11NO
• Molecular Weight: 137.181
• Mol File: 91597-62-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclobutanecarbonitrile, 3-ethenyl-3-methoxy-, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclobutanecarbonitrile, 3-ethenyl-3-methoxy-, cis-(91597-62-5)
• EPA Substance Registry System: Cyclobutanecarbonitrile, 3-ethenyl-3-methoxy-, cis-(91597-62-5)

Safety Data

• Hazardous Substances Data: 91597-62-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 51934-08-8 3-Vinylbicyclobutane-1-carbonitrile 

Relevant articles and documents

ADDITION REACTIONS TO BICYCLOBUTANE DERIVATIVES. THE REGIOSELECTIVITY OF THE ADDITION OF METHANOL AND METHANETHIOL TO 3-VINYLCYCLOBUTANE-1-CARBONITRILE

3-Vinylcyclobutane-1-carbonitrile adds anionoid nucleophiles (sodium methoxide and methanethiolate) in methanol strictly regioselectively at the central C-C bond with the formation of 3-vinyl-3-methoxy(methylthio)cyclobutane-1-carbonitrile (1,3-addition).The same substrate adds methanol under the catalytic influence of perchloric acid with the formation of both the 1,3-addition product and the 1,5-addition product, i.e., 3-(2-methoxyethylidene)cyclobutane-1-carbonitrile (with the regioisomers in a ratio of 3:2).