91644-89-2Relevant academic research and scientific papers
Zinc promoted simple and convenient synthesis of carbamates: An easy access for amino group protection
Yadav,Reddy, Gondi Sudershan,Reddy, M. Muralidhar,Meshram
, p. 3259 - 3262 (1998)
Synthesis of alkyl, aryl, heterocyclic, carbohydrate and amino acid carbamates is described. The protection of the amino group in the presence of other functionality in amino acids demonstrates the importance of this method.
A practical synthesis of carbamates using an 'in-situ' generated polymer-supported chloroformate
Mormeneo, David,Llebaria, Amadeu,Delgado, Antonio
, p. 6831 - 6834 (2007/10/03)
A versatile method for the synthesis of carbamates from an 'in-situ' generated polymer-supported chloroformate resin is presented. BTC (bis-trichloromethyl carbonate) is used as phosgene equivalent to afford a supported chloroformate, which, by sequential 'one-pot' reaction with a variety of alcohols and amines, furnishes the corresponding carbamates in high yields and purities. A versatile method for the synthesis of carbamates from an 'in-situ' generated polymer-supported chloroformate resin is presented. BTC (bis-trichloromethyl carbonate) is used as phosgene equivalent to afford a supported chloroformate, which, by sequential 'one-pot' reaction with a variety of alcohols and amines, furnishes the corresponding carbamates in high yields and purities.
