916485-43-3Relevant academic research and scientific papers
trans-cyclohexane-1,2-diamine is a weak director of absolute helicity in chiral nickel-salen complexes
Dong, Zhenzhen,Yap, Glenn P. A.,Fox, Joseph M.
, p. 11850 - 11853 (2007)
The interconversion between helical diastereomers of nickel-salen-based foldamers can be observed on a NMR time scale. Such complexes provide quantitative information about the propensity of different elements of central chirality to control the absolute
Control of absolute helicity in single-stranded abiotic metallofoldamers
Dong, Zhenzhen,Karpowicz Jr., Richard J.,Bai, Shi,Yap, Glenn P. A.,Fox, Joseph M.
, p. 14242 - 14243 (2008/03/13)
Described is the design, synthesis, and characterization of abiotic, single-stranded metallofoldamers that adopt helical secondary structures upon metal complexation. The absolute helicity is determined by stereocenters at the ends of the structures and i
