916853-95-7Relevant academic research and scientific papers
Nickel catalyzed Grob fragmentation: ω-dienyl aldehydes synthesis
Mori, Masahiko,Kimura, Masanari,Takahashi, Yushi,Tamaru, Yoshinao
, p. 4303 - 4305 (2006)
With a proper choice of phosphane ligands, a Ni(cod)2-phosphane catalyst promotes decarboxylative ring-opening reaction of a wide structural variety of cyclic carbonates 1 to give ω-dienyl aldehydes 2 in good yields. The Royal Society of Chemis
Palladium-catalyzed 1,3-diol fragmentation: Synthesis of ω-dienyl aldehydes
Kimura, Masanari,Mori, Masahiko,Tamaru, Yoshinao
, p. 4504 - 4506 (2008/04/01)
2-(1′-Hydroxy-2′-propenyl)cycloalkan-1-ols 1 undergo dehydrative C1-C2 bond cleavage and provide ω-dienyl aldehydes 2 under the catalysis of Pd(0) and 9-phenyl-9-BBN. The Royal Society of Chemistry.
