91704-75-5

Basic information

• Product Name: 1,2-Ethanediol, 1-cyclohexyl-1-phenyl-, (S)-
• CAS NO: 91704-75-5
• Molecular Formula: C14H20O2
• Molecular Weight: 220.312
• Mol File: 91704-75-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1,2-Ethanediol, 1-cyclohexyl-1-phenyl-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Ethanediol, 1-cyclohexyl-1-phenyl-, (S)-(91704-75-5)
• EPA Substance Registry System: 1,2-Ethanediol, 1-cyclohexyl-1-phenyl-, (S)-(91704-75-5)

Safety Data

• Hazardous Substances Data: 91704-75-5(Hazardous Substances Data)

Upstream product

• 5700-44-7 1-phenyl-1-cyclohexylethylene 
• 100-52-7 benzaldehyde 
• 931-51-1 cyclohexylmagnesiumchloride 
• 712-50-5 Cyclohexyl phenyl ketone 
• 20585-33-5 S-(+)-phenyl-2 cyclohexyl-2 hydroxy-2 acetate de methyle 
• 931-50-0 cyclohexylmagnesium bromide 
• 165879-50-5 (+)-(benzoyl)-2 phenyl-3 diazabicyclo-1,3 <3,3,O> octane 
• 20585-32-4 (S)-(+)-2-cyclohexyl-2-hydroxy-2-phenylacetaldehyde 
• 1074-12-0 phenylglyoxal hydrate 
• 20585-34-6 (S)-cyclohexylmandelic acid 

Downstream Products

• 31142-49-1 aldehyde 
• 20585-34-6 (S)-cyclohexylmandelic acid 
• 712-50-5 Cyclohexyl phenyl ketone 

Relevant articles and documents

An asymmetric dihydroxylation route to (S)-oxybutynin

An asymmetric synthesis of (S)-oxybutynin 1 is described using the Sharpless asymmetric dihydroxylation of α-cyclohexylstyrene as the key step.

Visible light-promoted dihydroxylation of styrenes with water and dioxygen

An efficient visible light promoted metal-free dihydroxylation of styrenes with water and dioxygen has been developed for the construction of vicinal alcohols. The protocol was operationally simple with a broad substrate scope. The mechanistic studies demonstrated that one of the hydroxyl groups came from water and the other one came from molecular oxygen. Additionally, the β-alkyoxy alcohols could also be obtained using a similar strategy.

Ligand-dependent reversal of facial selectivity in the asymmetric dihydroxylation

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