917376-80-8

Basic information

• Product Name: [RuH(κ-N,Se-selenomethimazolyl)(CO)(PPh3)2]
• Synonyms: [RuH(κ-N,Se-selenomethimazolyl)(CO)(PPh3)2]
• CAS NO: 917376-80-8
• Molecular Weight: 814.727
• Mol File: 917376-80-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RuH(κ-N,Se-selenomethimazolyl)(CO)(PPh3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [RuH(κ-N,Se-selenomethimazolyl)(CO)(PPh3)2](917376-80-8)
• EPA Substance Registry System: [RuH(κ-N,Se-selenomethimazolyl)(CO)(PPh3)2](917376-80-8)

Safety Data

• Hazardous Substances Data: 917376-80-8(Hazardous Substances Data)

Upstream product

• 132751-57-6 {hydridobis(acetonitrile)bis(triphenylphosphine)carbonylruthenium(II)}BF₄ 
• 157997-38-1 1,3-Dihydro-1-methyl-2H-imidazole-2-selone 

Downstream Products

• 917376-82-0 [Ru(CH=CHC6H4Me-4)(κ-N,Se-selenomethimazolyl)(CO)(PPh3)2] 

Relevant articles and documents

Templated synthesis and intact coordination of a diorganotriselenane: [RuCl2(PPh3){κ3-Se,N,N′-Se(mt Se)2}] (mtSe = selenomethimazolyl)

The reaction of [RuCl2(PPh3)3] with methimazole (Hmt) under basic conditions provides the simple bis(chelate) complex [Ru(κ2-S,N-mt)2(PPh3) 2], while the selenium analogue HmtSe provides an intact coordinated diorganotriselenane [Ru{κ3-Se,N,N′-Se(mt Se)2}Ch(PPh3)]. Bidentate mtSe coordination is however observed in the complexes [RuR(κ2-Se,N) (CO)-(PPh3)2] (R = H, CH=CHC6H 4Me-4).