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Phosphorus-derived chiral auxiliaries for α-alkylation of secondary amines by anodic oxidation
Sierecki, Emma,Turcaud, Serge,Martens, Thierry,Royer, Jacques
, p. 3199 - 3208 (2008/09/17)
Chiral phosphorus-based structures were investigated as N-activating groups for anodic oxidation and as chiral inductors. This first study presents the results obtained for pyrrolidine, with allyltrimethylsilane as a standard nucleophile. The methoxylated
