917893-63-1

Basic information

• Product Name: 2-Propenoic acid, 3-[2-[[(trifluoromethyl)sulfonyl]oxy]phenyl]-, ethyl ester, (2E)-
• CAS NO: 917893-63-1
• Molecular Formula: C12H11F3O5S
• Molecular Weight: 324.278
• Mol File: 917893-63-1.mol

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-[2-[[(trifluoromethyl)sulfonyl]oxy]phenyl]-, ethyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-[2-[[(trifluoromethyl)sulfonyl]oxy]phenyl]-, ethyl ester, (2E)-(917893-63-1)
• EPA Substance Registry System: 2-Propenoic acid, 3-[2-[[(trifluoromethyl)sulfonyl]oxy]phenyl]-, ethyl ester, (2E)-(917893-63-1)

Safety Data

• Hazardous Substances Data: 917893-63-1(Hazardous Substances Data)

Upstream product

• 91-64-5 coumarin 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 3943-94-0 (E)-ethyl 2-hydroxycinnamate 

Downstream Products

• 524937-26-6 ethyl (E)-4-[3'-(1-adamantyl)-4'-benzyloxyphenyl]-3-chlorocinnamate 
• 1185746-24-0 C₁₅H₂₀O₂ 
• 67176-94-7 1-phenyl-1,2-dihydro-2-quinolone 
• 917893-91-5 (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid (2-hydroxy-1,1-diphenyl-ethyl)-amide 
• 917893-79-9 2-{(4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-4,4-diphenyl-4,5-dihydro-oxazole 
• 917893-90-4 (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid (1-hydroxymethyl-cyclopentyl)-amide 
• 917893-78-8 2-{(4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-3-oxa-1-aza-spiro[4.4]non-1-ene 
• 917893-88-0 (4R,5S)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid ((S)-1-hydroxymethyl-2,2-dimethyl-propyl)-amide 
• 917893-87-9 (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid ((R)-1-hydroxymethyl-2-methyl-propyl)-amide 
• 917893-86-8 (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid ((S)-1-hydroxymethyl-2-methyl-propyl)-amide 
• 926627-23-8 (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-diethyl-[1,3]dioxolane-4-carboxylic acid (2-hydroxy-ethyl)-amide 
• 917893-89-1 (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid (2-hydroxy-1,1-dimethyl-ethyl)-amide 
• 917893-76-6 (S)-4-tert-Butyl-2-{(4R,5S)-5-[2-(diphenyl-phosphinoyl)-phenyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-4,5-dihydro-oxazole 
• 917893-72-2 2-{(4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-diethyl-[1,3]dioxolan-4-yl}-4,5-dihydro-oxazole 

Relevant articles and documents

StePHOX, a new family of optically active, tunable phosphine-oxazoline ligands: syntheses and applications

A new class of optically active phosphine-oxazoline ligands has been synthesized wherein backbone chirality of these new ligands is installed by a Sharpless asymmetric dihydroxylation. Different backbone protecting groups as well as different substitution patterns on the oxazoline ring were studied. These ligands were tested in allylic substitution (with ee's up to 97%) and asymmetric Tsuji allylation.

An efficient route from coumarins to highly functionalized N-phenyl-2-quinolinones via Buchwald-Hartwig amination

Multiple substituted N-phenyl-2-quinolinones were obtained in a convenient four-step route from a variety of commercially available coumarins, utilizing customised Buchwald-Hartwig amination protocols for the key reaction. Whereas simple aminolysis of cou