926627-23-8

Basic information

• Product Name: (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-diethyl-[1,3]dioxolane-4-carboxylic acid (2-hydroxy-ethyl)-amide
• Synonyms: (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-diethyl-[1,3]dioxolane-4-carboxylic acid (2-hydroxy-ethyl)-amide
• CAS NO: 926627-23-8
• Molecular Weight: 493.54
• Mol File: 926627-23-8.mol

Chemical Properties

• CAS DataBase Reference: (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-diethyl-[1,3]dioxolane-4-carboxylic acid (2-hydroxy-ethyl)-amide(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-diethyl-[1,3]dioxolane-4-carboxylic acid (2-hydroxy-ethyl)-amide(926627-23-8)
• EPA Substance Registry System: (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-diethyl-[1,3]dioxolane-4-carboxylic acid (2-hydroxy-ethyl)-amide(926627-23-8)

Safety Data

• Hazardous Substances Data: 926627-23-8(Hazardous Substances Data)

Upstream product

• 917893-63-1 ethyl (trifluoro-methane-sulfonyloxy)cinnamate 
• 91-64-5 coumarin 
• 917893-68-6 (4S,5R)-2,2-Diethyl-5-(2-trifluoromethanesulfonyloxy-phenyl)-[1,3]dioxolane-4-carboxylic acid ethyl ester 
• 917893-64-2 (2S,3R)-2,3-Dihydroxy-3-(2-trifluoromethanesulfonyloxy-phenyl)-propionic acid ethyl ester 
• 917893-70-0 (4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-diethyl-[1,3]dioxolane-4-carboxylic acid ethyl ester 
• 141-43-5 ethanolamine 
• 3943-94-0 (E)-ethyl 2-hydroxycinnamate 

Downstream Products

• 917893-72-2 2-{(4S,5R)-5-[2-(Diphenyl-phosphinoyl)-phenyl]-2,2-diethyl-[1,3]dioxolan-4-yl}-4,5-dihydro-oxazole 

Relevant articles and documents

StePHOX, a new family of optically active, tunable phosphine-oxazoline ligands: syntheses and applications

A new class of optically active phosphine-oxazoline ligands has been synthesized wherein backbone chirality of these new ligands is installed by a Sharpless asymmetric dihydroxylation. Different backbone protecting groups as well as different substitution patterns on the oxazoline ring were studied. These ligands were tested in allylic substitution (with ee's up to 97%) and asymmetric Tsuji allylation.