91791-27-4

Basic information

• Product Name: (+/-)-(Z)-2-hydroxy-1-phenyl-1-propanone oxime
• Synonyms: (+/-)-(Z)-2-hydroxy-1-phenyl-1-propanone oxime
• CAS NO: 91791-27-4
• Molecular Weight: 165.192
• Mol File: 91791-27-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+/-)-(Z)-2-hydroxy-1-phenyl-1-propanone oxime(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(Z)-2-hydroxy-1-phenyl-1-propanone oxime(91791-27-4)
• EPA Substance Registry System: (+/-)-(Z)-2-hydroxy-1-phenyl-1-propanone oxime(91791-27-4)

Safety Data

• Hazardous Substances Data: 91791-27-4(Hazardous Substances Data)

Upstream product

• 5650-40-8 2-hydroxypropiophenone 

Downstream Products

• 19901-87-2 (+/-)-erythro-1-amino-1-phenyl-2-propanol 
• 19901-87-2 (+/-)-threo-1-amino-1-phenyl-2-propanol 

Relevant articles and documents

Halogen-bonded iodonium ion catalysis: A route to α-hydroxy ketones: Via domino oxidations of secondary alcohols and aliphatic C-H bonds with high selectivity and control

A domino synthesis of α-hydroxy ketones has been developed from benzylic secondary alcohols employing catalytic iodonium ions stabilized by DMSO. The reaction proceeds through an unprecedented sequential oxidation of alcohols to ketone and its α-hydroxylation in a controlled manner. The spectroscopic evidence establishes the possibility of formation of a stable halogen-bonded adduct between DMSO and iodonium ions.