91850-96-3

Upstream product

• 79866-39-0 2-(tert-butylamino)-1-phenylethanone hydrochloride 
• 1074-12-0 phenylglyoxal hydrate 
• 75-64-9 tert-butylamine 
• 1075-06-5 2,2-dihydroxy-1-phenyl-ethanone 
• 532-27-4 1-chloroacetophenone 

Downstream Products

• 106114-54-9 {C₂H₅Zn(C₂H₅)((CH₃)3C)NC(H)C(C₆H₅)O}2 
• 1262406-50-7 C₁₆H₂₄F₃NOSi 
• 14467-32-4 (1S)-2-(tert-butylamino)-1-phenylethanol 
• 151268-44-9 [Fe(CO)3(C(CH₃)3NCHCC₆H₅O)] 
• 151268-66-5 Fe₂(CO)6((CH₃)3CNCHCOC₆H₅) 
• 17685-52-8 triiron dodecarbonyl 
• 106138-91-4 {C₃H₇Zn(C₃H₇)(CH₃)3CNCHC(C₆H₅)O}2 
• 108120-18-9 ((CH₃)2Al(CH₃)3CNCHC(C₆H₅)(CH₃)O)2 
• 14467-51-7 (R)-1-Phenyl-2-(tert-butylamino)-1-ethanol 
• 14467-32-4 2-(tert-butylamino)-1-phenylethan-1-ol 

Relevant academic research and scientific papers

Enantioselective additions of (trifluoromethyl)trimethylsilane to α-imino ketones derived from aryl glyoxals

Chemoselective additions of (trifluoromethyl)trimethylsilane to α-imino ketones derived from aryl glyoxals in the presence of a catalytic amount of enantiomerically pure ammonium bromides, derived from Cinchona alkaloids and K2CO3 le

Asymmetric synthesis of β-amino alcohols by the transfer hydrogenation of α-keto imines

The asymmetric transfer hydrogenation of representative aryl and benzofuranyl 2-tert-butylaminoethanones with formic acid-triethylamine, catalyzed by RhCl[(R,R)-TsDPEN](C5Me5), produced the corresponding β-tert-butylamino alcohols in 97-99% ee. A short asymmetric synthesis of (R)-bufuralol, a potent β-adrenergic receptor antagonist, is described. This approach to β-amino alcohols from ketones circumvents the halogenation-reduction-amination sequence.

Reactions of α-imino ketones derived from arylglyoxals with (trifluoromethyl)trimethylsilane; A new route to β-amino-α- trifluoromethyl alcohols

The reactions of α-imino ketones, derived from arylglyoxals, with (trifluoromethyl)trimethylsilane (CF3SiMe3) in DME solution, in the presence of catalytic amount of CsF, at room temperature, yield O-silylated β-imino alcohols in the

The Reaction of Phenylglyoxal with Primary Aliphatic and Aromatic Amines. Synthesis of Phenylglyoxal Monoimines and some Derivatives.

Condensation of phenylglyoxal with primary aliphatic amines yields the related keto-aldimines.When primary aromatic amines are used, aldimines, amino-hydroxy-ketones, diamino-ketones, and alkoxy-amino-ketones are obtained depending upon the nature of the amine and the experimental conditions.Alternatively the monoimines can be obtained by dehydration of C-hydroxyphenacylarylamines and by demethanolation of C-methoxyphenacylarylamines both on treatment with Pd/C catalyst.Reduction of phenylglyoxal monoimines with sodium borohydride yielded H-substituted 1-phenyl-2-aminoethanols and 1,3-dipolar cycloaddition of the imines with p-chlorobenzonitrile oxide afforded 4-substituted 5-benzoyl-3-(p-chlorophenyl)-4,5-dihydro-1,2,4-oxadiazoles.

Removal of Toluene-p-sulphonyl Groups from Sulphonamides. Part 4. Synthesis of Phenylglyoxal Imine Monomers

Syntheses and reactions of N-tosylphenacylamines with bases have been systematically examined.Monomeric C-methoxy-imines are available from some of these reactions.C-Methoxyphenacylarylamines, made by two routes, were converted into monomeric imines on treatment with noble-metal catalysts, The boron trifluoride-catalysed reactions of aryl aldehydes with sulphonamides provide a new and convenient route to N-sulphonylarylimines.