919293-28-0Relevant articles and documents
Catalytic asymmetric conjugate addition of isocyanoacetate to (Z)-3-substituted-2-(4-pyridyl)-acrylonitrile, a reactive class of Michael acceptor
Del Fiandra, Claudia,Moccia, Maria,Cerulli, Valentina,Adamo, Mauro F. A.
, p. 1697 - 1700 (2016)
(Z)-3-Substituted-2-(4-pyridyl)-acrylonitriles, a reactive class of Michael acceptors obtained exclusively as a single (Z) isomer, reacted with un-substituted isocyanoacetate esters mediated by phase-transfer catalysis to give, after base promoted cyclisation, functionalized imines in up to 94% ee and as a single diastereoisomer.
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Page/Page column 57, (2008/06/13)
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