91940-09-9

Basic information

• Product Name: Benzene, (2-octenylsulfonyl)-, (E)-
• CAS NO: 91940-09-9
• Molecular Formula: C14H20O2S
• Molecular Weight: 252.378
• Mol File: 91940-09-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, (2-octenylsulfonyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-octenylsulfonyl)-, (E)-(91940-09-9)
• EPA Substance Registry System: Benzene, (2-octenylsulfonyl)-, (E)-(91940-09-9)

Safety Data

• Hazardous Substances Data: 91940-09-9(Hazardous Substances Data)

Upstream product

• 618-41-7 Benzenesulfinic acid 
• 22104-78-5 2-octenol 
• 91789-07-0 (cis-Oct-2-enyl) phenyl sulfide 

Downstream Products

• 113460-94-9 (1'S*,2'E,3R*)-3-<3'-(phenylsulfonyl)-1'-pentylprop-2'-enyl>butan-4-olide 
• 113460-93-8 (1'S*,2'E,3R*)-3-<1'-(phenylsulfonyl)oct-2'-enyl>butan-4-olide 
• 113460-93-8 (1'R*,2'E,3R*)-3-<1'-(phenylsulfonyl)oct-2'-enyl>butan-4-olide 
• 113460-94-9 (1'R*,2'E,3R*)-3-<3'-(phenylsulfonyl)-1'-pentylprop-2'-enyl>butan-4-olide 
• 113460-93-8 (1'S*,2'Z,3R*)-3-<1'-(phenylsulfonyl)oct-2'-enyl>butan-4-olide 
• 113460-93-8 (1'R*,2'Z,3R*)-3-<1'-(phenylsulfonyl)oct-2'-enyl>butan-4-olide 

Relevant articles and documents

Reciprocal-Activation Strategy for Allylic Sulfination with Unactivated Allylic Alcohols

A reciprocal-activation strategy for allylic sulfination with unactivated allylic alcohols was developed. In this reaction, the hydrogen bond interaction between allylic alcohols and sulfinic acids allowed for reciprocal activation, which enabled a dehydrative cross-coupling process to occur under mild reaction conditions. This reaction worked in an environmentally friendly manner, yielding water as the only byproduct. A variety of allylic sulfones could be obtained in good to excellent yields with wide functional group tolerance. In gram scale reactions, allylic sulfones could be conveniently isolated in high yield by filtration.