91789-07-0Relevant academic research and scientific papers
Direct synthesis of allyl sulfides from allyl alcohols and thiols
Tsay,Lin,Furth,Shum,King,Yu,Chen,Hwu
, p. 329 - 334 (2007/10/02)
In the presence of boron trifluoride-diethyl ether complex, various allyl alcohols [(-)-myrtenol, geraniol, cinnamyl alcohol, linalool, 1-octen-3-ol, 2-hydroxybenzyl alcohol and bicyclic diols] were reacted with thiophenol, 1-butanethiol, trimethyl(phenylthio)silane or hexamethylsilane in dichloromethane at room temperature to give the corresponding allyl sulfides in good to excellent yields. The mild conditions for this transformation allowed chemoselectivity.
The Preparation of Some Octenyl Sulfides from Oct-1-en-3-ol and Oct-2-en-1-ol
Binns, Malcolm R.,Haynes, Richard K.,Lambert, Dale E.,Schober, Paul A.,Turner, Susan G.
, p. 281 - 290 (2007/10/02)
(E)- and (Z)-1-(Phenylthio)oct-2-ene, (E)-1-(methylthio)- and 1-(t-butylthio)-oct-2-ene, S- N,N-dimethylthiocarbamate, S- N,N-dimethylthiocarbamate, (E)-(oct-2-enylthio)benzothiazole, and S- N,N,N',N'-tetramethylphosphorodiamidothioate have been prepared by nucleophilic substitution reactions and - and -sigmatropic shifts involving intermediates prepared from oct-1-en-3-ol and (E)- and (Z)-oct-2-en-1-ol.
