91946-87-1Relevant academic research and scientific papers
AN UNUSUAL NITROSYL-DIAZOALKANE COUPLING REACTION. SYNTHESIS, STRUCTURE AND REACTIVITY OF THE ALDOXIME-DINITROGEN COMPLEX, OsCl2(N2)(PPh3)2
Gallop, M. A.,Rickard, C. E. F.,Roper, W. R.
, p. C21 - C24 (1984)
Reaction of OsCl(NO)(PPh3)3 with IC(N2)CO2Et gives a purple species which, on treatment with HCl, affords OsCl2(N2)(PPh3)2.This aldoxime-dinitrogen complex, structurally characterized by X-ray crystallography, is thought to arise from a coup
