AN UNUSUAL NITROSYL-DIAZOALKANE COUPLING REACTION. SYNTHESIS, STRUCTURE AND REACTIVITY OF THE ALDOXIME-DINITROGEN COMPLEX, OsCl2(N2)(PPh3)2

DOI: 10.1016/0022-328X(84)80299-5

Source and publish data:

Journal of Organometallic Chemistry p. C21 - C24 (1984)

Update date:2022-08-04

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Authors:

Gallop, M. A.

Rickard, C. E. F.

Roper, W. R.

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Article abstract of DOI:10.1016/0022-328X(84)80299-5

Reaction of OsCl(NO)(PPh3)3 with IC(N2)CO2Et gives a purple species which, on treatment with HCl, affords OsCl2(N2)(PPh3)2.This aldoxime-dinitrogen complex, structurally characterized by X-ray crystallography, is thought to arise from a coup

Full text of DOI:10.1016/0022-328X(84)80299-5

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Product name:OsCl₂(CO)[NCCO₂CH₂CH₃](P(C₆H₅)3)2

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