AN UNUSUAL NITROSYL-DIAZOALKANE COUPLING REACTION. SYNTHESIS, STRUCTURE AND REACTIVITY OF THE ALDOXIME-DINITROGEN COMPLEX, OsCl2(N2)(PPh3)2

DOI: 10.1016/0022-328X(84)80299-5

Source and publish data:

Journal of Organometallic Chemistry p. C21 - C24 (1984)

Update date:2022-08-04

Topics:

Authors:

Gallop, M. A.

Rickard, C. E. F.

Roper, W. R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(84)80299-5

Reaction of OsCl(NO)(PPh3)3 with IC(N2)CO2Et gives a purple species which, on treatment with HCl, affords OsCl2(N2)(PPh3)2.This aldoxime-dinitrogen complex, structurally characterized by X-ray crystallography, is thought to arise from a coup

Full text of DOI:10.1016/0022-328X(84)80299-5

Products guided by the article

Product name:OsCl₂(CO)[NCCO₂CH₂CH₃](P(C₆H₅)3)2

Cas No:91946-87-1

R&D Labs maybe for 91946-87-1

Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd

Contact:+86-533-5415882

Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Shao Xing Empire Import&Export CO.,ltd

Contact:86-575-82127757

Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China
Xi'an caijing Opto-Electrical Science & Technology Co., LTD

Contact:+86-29-88294447

Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China

Relevant to this article

N-<(TRIORGANYLSILYL)ALKYL>ETHYLENEDIAMINES

Doi:10.1016/0022-328X(84)85094-9
(1984)
An Efficient Method for the Preparation of Carbapenem Derivatives with C-2 Carbon Side Chains from PS-5 and OA-6129 Compounds

Doi:10.1039/c39840001513
(1984)
Reaction of Organolithium Reagents with Lactim Ethers: Preparation of Cyclic 2-Alkyl Imines or 2,2-Dialkyl Amines

Doi:10.1021/jo00197a013
(1984)
Palladium-catalysed Transfer Hydrogenation of Azobenzenes and Oximes using Ammonium Formate

Doi:10.1039/a705957d
(1998)
Synthesis of Cyclic Azomethine Imines from Aza β-Lactams. Conversion of 3-Oxo-1,2-diazetidinium Tosylates into 1-Substituted 3-Oxo-1,2-diazetidinium Inner Salts

Doi:10.1021/jo00172a025
(1983)
Synthesis of the novel sulfur-containing analgesic S-etorphine

Doi:10.1248/cpb.32.1268
(1984)

Article Doi