92039-80-0

Basic information

• Product Name: 1-Phenyl-cycloheptanon-⁽²⁾-oxim
• Synonyms: 1-Phenyl-cycloheptanon-⁽²⁾-oxim
• CAS NO: 92039-80-0
• Molecular Weight: 203.284
• Mol File: 92039-80-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Phenyl-cycloheptanon-⁽²⁾-oxim(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Phenyl-cycloheptanon-⁽²⁾-oxim(92039-80-0)
• EPA Substance Registry System: 1-Phenyl-cycloheptanon-⁽²⁾-oxim(92039-80-0)

Safety Data

• Hazardous Substances Data: 92039-80-0(Hazardous Substances Data)

Upstream product

• 14996-78-2 2-phenylcycloheptanone 
• 5470-11-1 hydroxylamine hydrochloride 

Downstream Products

• 1372804-69-7 8-phenylazocan-2-one 
• 95867-38-2 7,7-diphenylheptanoic acid amide 

Relevant articles and documents

One-Pot Reductive Allylation of Amides by Using a Combination of Titanium Hydride and an Allylzinc Reagent: Application to a Total Synthesis of (-)-Castoramine

A one-pot direct reductive allylation protocol has been developed for the synthesis of secondary amines by using titanium hydride and an allylzinc reagent. This protocol is applicable to a broad range of substrates, including acyclic amides, benzamides, α,β-unsaturated amides, and lactams. The stereochemical outcome obtained from the reaction with crotylzinc reagent suggested that the allylation reaction proceeds through a six-membered cyclic transition state. A total synthesis of (-)-castoramine was accomplished by following this protocol for the highly stereoselective construction of contiguous stereocenters.