92050-09-4Relevant academic research and scientific papers
Nitrones and Oxaziridines. XXXVIII. Nitric Acid Oxidation of Some Pyrroline 1-Oxides
Black, David St.C,Strauch, Richard J.
, p. 1613 - 1619 (2007/10/02)
2,4-Diaryl-5,5-dimethyl-1-pyrroline 1-oxides (5)-(7) undergo smooth oxidation by concentrated nitric acid in acetonitrile to give the hydroxy ketones (9)-(11).Reduction of compound (10) with sodium borohydride gives the diol (22), which can be dehydrated
Reaction of γ-Nitro Ketones with Thionyl Chloride: Formation and X-Ray Crystal Structure of an α-Sulfinyl Ketone
Black, David St. C.,Fallon, Gary D.,Gatehouse, Bryan M.,Wishart, John D.
, p. 777 - 784 (2007/10/02)
Reaction of thionyl chloride on 4-methyl-4-nitro-1-phenylpentan-1-one (2) yields 4-methyl-4-nitro-1-phenyl-2-thioxopentan-1-one S-oxide (4), the structure of which has been clarified by X-ray crystallography.The corresponding methoxyphenyl compound (10) h
