920979-35-7Relevant academic research and scientific papers
Au-catalyzed reaction of propargylic sulfides and dithioacetals
Peng, Lingling,Zhang, Xiu,Zhang, Shiwei,Wang, Jianbo
, p. 1192 - 1197 (2007/10/03)
(Chemical Equation Presented) Propargylic sulfides and dithioacetals are found to undergo similar transformations as propargylic carboxylates when catalyzed by AuCl or AuCl3, affording indene derivatives through pentannulation of aromatic rings
A convenient synthesis of propargylic dithioacetals
Huang, Li-Fu,Lee, Chin-Fa,Tseng, Jui-Chang,Luh, Tien-Yau
, p. 3173 - 3175 (2008/02/13)
Treatment of trimethylsilyl-substituted alkynyl ketones with 1,2-ethanedithiol in the presence of BF3·OEt2 in methanol afforded the corresponding dithioacetal. Removal of the silyl group under basic conditions followed by palladium-catalyzed coupling reactions with aryl iodides yielded the corresponding propargylic dithioacetals in excellent yield. Georg Thieme Verlag Stuttgart.
