92121-12-5

Upstream product

• 75142-63-1 2-<(trimethylsilyl)methyl>cyclohexanone 
• 67-56-1 methanol 

Downstream Products

• 216022-89-8 (2E,7E)-2-((S)-4-Benzyl-2-oxo-oxazolidine-3-carbonyl)-9-trimethylsilanyl-nona-2,7-dienoic acid methyl ester 
• 73899-78-2 (+)-brefeldin C 
• 135330-03-9 (E)-(R)-7-{(1S,2R)-2-[2-(4-Methoxy-phenyl)-[1,3]dioxolan-4-yl]-cyclopentyl}-hept-6-en-2-ol 
• 126761-01-1 (E)-(R)-4-[(1R,2S)-2-((E)-(R)-6-Hydroxy-hept-1-enyl)-cyclopentyl]-4-(4-methoxy-benzyloxy)-but-2-enoic acid 
• 126761-02-2 (5E,13E)-(3aR,4R,9S,14aS)-4-(4-Methoxy-benzyloxy)-9-methyl-2,3,3a,9,10,11,12,14a-octahydro-1H,4H-8-oxa-cyclopentacyclotridecen-7-one 
• 135330-05-1 (E)-(R)-4-[(1R,2S)-2-((E)-(R)-6-Hydroxy-hept-1-enyl)-cyclopentyl]-4-(4-methoxy-benzyloxy)-but-2-enoic acid methyl ester 

Relevant academic research and scientific papers

Silicon-directed Norrish Type I Cleavage of β-Trimethylsilyl Cycloalkanones

The Me3Si group in β-trimethylsilyl cycloalkanones was able to direct the Norrish type I cleavage by providing regioselectivity in the C-1-C-2 bond cleavage and by increasing the quantum yield and the reaction rate.

Intramolecular ene and related reactions, Part 9. Photochemically induced synthesis of allylsilane carbaldehydes

Allylsilane carbaldehydes are valuable substrates for the tandem Koevenagel allylsilane and iminium cyclization. They can easily be prepared by a photochemical α-cleavage of cyclic ketones bearing a trimethylsilylmethyl group in the α-position (Norrish Ty